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Sesquicamphanes

Asa result of the studies outlined above, additional stereochemical conclusions can be drawn. Firstly, folding of the acyclic chain of the C15 precursor is as in (24) rather than (25) in all cases [as has been previously demonstrated in other examples (1974, 1975)]. Secondly the labelling pattern favours the intermediacy of the Cu ring system (42) rather than bisabolene-like (43) or sesquicamphane-like (44) intermediates as has been suggested by other workers. Thirdly a penetrating stereochemical analysis led to the conclusion that formation of ( —)-longifolene and... [Pg.190]

See other pages where Sesquicamphanes is mentioned: [Pg.60]    [Pg.374]    [Pg.17]    [Pg.89]    [Pg.93]    [Pg.364]    [Pg.12]    [Pg.73]    [Pg.96]    [Pg.145]    [Pg.60]    [Pg.374]    [Pg.17]    [Pg.89]    [Pg.93]    [Pg.364]    [Pg.12]    [Pg.73]    [Pg.96]    [Pg.145]   
See also in sourсe #XX -- [ Pg.96 , Pg.145 ]



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Bisabolanes, Sesquicamphanes, Santalanes, and Carotanes

Sesquipinane, Sesquicamphane

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