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Sequence, liquid chromatography methods

Lipczynska-Kochany, E., and J.R. Botton (1992), Elash photolysis/high-performance liquid chromatography method for studying the sequence of photochemical reactions Direct photoylsis of phenol. Environ. Sci. Technol., 26, 2524—2527. [Pg.1437]

In the present context correlation means chemically relating a compound of unknown configuration with a compound of known relative configuration. In this section correlation sequences which do not directly affect the chiral units are discussed. Relations of this type, if carefully applied, are unambiguous and do not depend on mechanistic and/or stereochemical assumptions (also see Sections 4.3.4.1.2. and 4.3.4.1.2.1.). In contrast to the constraints in methodology mentioned in Section 4.3.4.1.2., comparison with the reference sample can be performed by any suitable analytical method, such as gas or liquid chromatography, or NMR spectroscopy. Some examples are ... [Pg.469]


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