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Semi-coordination

While the range of copper(II) complexes involving Cu—Br bonds (Table 81c) is more limited than those for Cu—Cl bonds (Table 81b), the structures tend to be analogous, with short Cu—Br distances of 2.4 A and long distances of ca. 3.0 A. Simple iodine complexes of the copper(II) ion are unknown, in view of the ready reduction of copper(II) to copper(I) with the liberation of iodine, nevertheless, copper-iodine bonds are formed if the copper(II) ion is stabilized by complex formation, as in [Cu(bipy)2I]I (420),1299 the structure of which involved the first example of five-coordinate copper(II) stereochemistry.1300 Semi-coordinate iodide... [Pg.741]

See other pages where Semi-coordination is mentioned: [Pg.221]    [Pg.756]    [Pg.604]    [Pg.604]    [Pg.621]    [Pg.625]    [Pg.632]    [Pg.636]    [Pg.637]    [Pg.640]    [Pg.642]    [Pg.688]    [Pg.726]    [Pg.729]    [Pg.730]    [Pg.738]    [Pg.739]    [Pg.739]    [Pg.739]    [Pg.741]    [Pg.419]    [Pg.419]    [Pg.426]    [Pg.106]    [Pg.357]    [Pg.509]    [Pg.52]    [Pg.54]    [Pg.55]    [Pg.55]    [Pg.59]    [Pg.53]    [Pg.1065]    [Pg.1065]    [Pg.1072]    [Pg.5477]    [Pg.5477]    [Pg.5494]    [Pg.5498]    [Pg.5505]    [Pg.5509]    [Pg.5510]    [Pg.5513]    [Pg.5515]    [Pg.5561]    [Pg.5599]    [Pg.5602]    [Pg.5603]    [Pg.5611]   


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Complexes semi-coordinate

Complexes semi-coordinated ligands

Semi-coordination copper complexes

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