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Semi-Cluster Expansion Theories for the Open-Shell States

SEMI-CLUSTER EXPANSION THEORIES FOR THE OPEN-SHELL STATES [Pg.310]

When the number of valence electrons are far less in comparison to the number of core electrons, the bulk of the size—extensivity of the total energy [Pg.310]

5) indicates that 4 k receives contribution from the correlating virtual determinants in [Pg.312]

IT+n the core-reorganization and core-correlation changes attendant with the addition of valence holes and/or particles are not very severe, then a [Pg.312]

As the name indicates, these methods determine the coefficients C by an appeal to the variational principle for the state energies E We shall discuss two principal formalisms which make use of this strategy. [Pg.313]




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Cluster open clusters

Clusters expansion

Clusters open-shell

Expansions for

Open shell

Open- shell states

Semi-cluster expansion theories

The Cluster Expansion

The expansion

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