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Sellmann-type metal complexes

Quantum Chemical Investigations into the Problem of Biological Nitrogen Fixation Sellmann-Type Metal-Sulfur Model Complexes Markus Reiher and Bernd A. Hess... [Pg.653]

QUANTUM CHEMICAL INVESTIGATIONS INTO THE PROBLEM OF BIOLOGICAL NITROGEN FIXATION SELLMANN-TYPE METAL-SULFUR MODEL COMPLEXES... [Pg.55]

SELLMANN-TYPE METAL-SULFUR MODEL COMPLEXES... [Pg.59]

Coming back to the strength of hydrogen bonding in the more complicated dinuclear complexes, we note that our dinuclear Sellmann-type metal diazene complexes were chosen closely following the lines... [Pg.70]

In 2004 and 2005 the photochemical activation of dinitrogen with transition metal model complexes of the Sellmann type nitrogenase was studied using CPMD [193, 194], A dinuclear complex — designed to emulate the open-side FeMoco model -was simulated. Several side reactions were observed which have to be suppressed in order to arrive at the reduced species [194]. Chelate effects and their partial dissociation as well as low temperatures led to successful events. An optimized design of the complexes to inhibit side reactions was suggested [194]. [Pg.142]

See other pages where Sellmann-type metal complexes is mentioned: [Pg.55]    [Pg.61]    [Pg.55]    [Pg.61]    [Pg.61]    [Pg.81]    [Pg.88]    [Pg.132]    [Pg.74]    [Pg.75]    [Pg.75]    [Pg.128]   
See also in sourсe #XX -- [ Pg.61 , Pg.62 , Pg.63 ]



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