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Self-organizing rod-coil copolymers

TARKKA ET AL. Self-Organizing Rod-Coil Copolymer Systems... [Pg.477]

Figure 1. Schematic illustration of the protein-like folding (7 of an electroluminescent ternary rod-coil copolymer. The resulting self-organized nanostructure varies with copolymer composition (10),... Figure 1. Schematic illustration of the protein-like folding (7 of an electroluminescent ternary rod-coil copolymer. The resulting self-organized nanostructure varies with copolymer composition (10),...
Figure 23 AFM amplitude image of block copolymer 21a thin film on mica cast from TFA/CHCI3 (a) 30 70v/v and (c) 3 97 v/v, and annealed in the solvent vapor, (b, d) Schematic representation of self-organization of coil-rod-coil block copolymers and possible packing scheme in thin film. Reprinted with permission from Kong, X. Jenekhe, S. A. Macromolecules 2MA, 37.8180-8183, Copyright 2004 American Chemical Society. ... Figure 23 AFM amplitude image of block copolymer 21a thin film on mica cast from TFA/CHCI3 (a) 30 70v/v and (c) 3 97 v/v, and annealed in the solvent vapor, (b, d) Schematic representation of self-organization of coil-rod-coil block copolymers and possible packing scheme in thin film. Reprinted with permission from Kong, X. Jenekhe, S. A. Macromolecules 2MA, 37.8180-8183, Copyright 2004 American Chemical Society. ...
Rod-coil diblock copolymers with a relatively short rod segment self-assembled into a wavy-lamellar morphology, while increasing the rod fraction resulted in the formation of a zigzag lamellar phase. At rod fractions/phic of 0-96 and 0.98, the PS coils were found to organize into arrowhead-shaped domains embedded in a PHIC matrix. Unlike the self-assembly of the PPP-17-PS and PPQ-b-PS diblock copolymers, the unconventional morphologies discovered for the PHIC-I7-PS rod-coils are related to their macromolecular architecture and are... [Pg.753]


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See also in sourсe #XX -- [ Pg.475 , Pg.476 ]




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