Self exchange cobalt hexaamines

Table 10.2. Observed and calculated electron self-exchange rates of hexaamine cobalt(III/II) complexes11321.

Fig. 12. Plot of number of amine protons versus log of the self-exchange rate constant (M s ) for cobalt hexaamine complexes at 25°C. No correction has been made for ionic strength differences. The data include some nonhomoleptic complexes. (1) [CoCNHslg], (2) [Co(en)3]3+ 2+, (3) [Co(chxn) ] + 2+ (4) [Co(tmen) ]3+ 2+, (5) [Co(dien)"]"+ 2+, (6) [Co(pet) P+ 2+, (7) [Co(linpen)P" 2 + (g) lCo(medien)(9) [Co(tacn)(dien)]3+ 2+, (10) [Co(tacn) (pet) (11) [Co(tacn) (etdien) (12) [Co(tacn) (budien) p+ 2+ 3 [Co(tacn)(medien)P, (14) [Co(diAmsar)] , (15) [Co(taptacn)P, (16) [Co(metacn) ] 2+, (17) [Co(diAmsar)P 2+, (18) [Co(sar)(19) [Co(sep)P 2, (20) [Co(dtne)] , (21) [Co(Amsartacn)], (22) [Co(Amsartacn)] , (23) [Co-(diAmchxnsar)] , (24) [Co(diAmchxnsar)] . The data for homoleptic complexes are taken from Table IV the other data are from reference U02). The line was calculated without the data for the sep and sar derivative cages and the [Coftmenls] couple.

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See also in sourсe #XX -- [ ]

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