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Selenoxides dihydroxylation

DIHYDROXYLATION Osmium tetroxide-Dihydroquinine acetate. Osmium tetrox-ide-Diphenyl selenoxide. Osmium tetroxide-Trimethylamine N-oxide-Pyiidine. Thallium(l) acetate-iodine. Triphenylmethylphosphonium permanganate. [Pg.468]

Table 7 Asymmetric dihydroxylation of a-methyl styrene with different selenoxides as co oxidants ... Table 7 Asymmetric dihydroxylation of a-methyl styrene with different selenoxides as co oxidants ...
In another development, Krief has shown that selenoxides (especially aryl/alkyl selenoxides) are capable of replacing amine-oxides as the reoxidant in the dihydroxylation reaction. An asymmetric process based on (DHQD)2PHAL (named SeOAD) was also developed and this gave good to excellent ee s with a range of alkenes." ... [Pg.269]

See other pages where Selenoxides dihydroxylation is mentioned: [Pg.291]    [Pg.403]    [Pg.417]    [Pg.737]    [Pg.104]    [Pg.82]   
See also in sourсe #XX -- [ Pg.250 , Pg.251 , Pg.252 , Pg.253 ]



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