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Selective Intramolecular Epoxidations Directed by Removable Tethers

4 Selective Intramolecular Epoxidations Directed by Removable Tethers [Pg.171]

This template directed functionalization of double bonds within reach was also used to determine the conformational preferences of some terpene polyenes [62], As in the previously described work with attached benzophenone reagents, the selective template-directed epoxidations revealed the details of chain folding in flexible molecules. [Pg.172]

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Direct selection

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Directional selection

Epoxidation selectivity

Epoxidations, directed

Epoxide selectivity

Epoxides directed epoxidation

Intramolecular epoxidations

Intramolecular selectivity

Selective epoxidation

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