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Schiff base complexes, osmium

Other chiral metal catalysts such as iridium, osmium, and rhenium catalysts have also been utilized for asymmetric cyclopropanation. In particular, iridium catalyst gave exceptional enantio- and diastereoselectivities. Chiral Ir(III) salen complexes, which contain a-coordinated aryl ligands, were found to catalyze the cyclopropanation of st3rrene derivatives with TDA. Higher yields (99%), higher diastereoselectivity t/c = 1 99), and enantioselectivity (99% ee) were observed when the reactions were conducted at lower temperature (—78°C) (98). For osmium, an Schiff-based complex of [Os(fBu-salch)(OH)Cl] (H2tBu-salch... [Pg.889]


See other pages where Schiff base complexes, osmium is mentioned: [Pg.389]    [Pg.178]    [Pg.764]    [Pg.820]    [Pg.178]    [Pg.3367]    [Pg.432]    [Pg.2512]    [Pg.432]    [Pg.3366]    [Pg.152]    [Pg.336]    [Pg.321]    [Pg.250]    [Pg.524]    [Pg.452]   
See also in sourсe #XX -- [ Pg.265 ]




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Osmium complexes

Schiff bases complexes

Schiffs Base Complexes

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