Scandium complexes 2,2 -bipyridyl

Scandium complexes, 1059-1116 alkoxides, 1065 amides, 1062,1066 amine oxides, 1065 amines, 1060 amino acids, 1066 aromatic amines, 1061 arsenic compounds, 1065 2,2 -bipyridyl, 1061... 

Rare earth arene complexes are good precursors for difficult-to-synthesize rare earth compounds (Bochkarev, 2002) and the same was true for the scandium arene complexes supported by NN . Hessen previously showed that a scandium complex of the 2,2 -bipyridyl radical anion could be readily accessed from a reduced 1,3-diene scandium complex (Beetstra et al., 2003). Similarly, the addition of 2,2 -bipyridine to a CeDs solution of Sc2-naph (Scheme 3A) led to the formation of the previously reported radical anionic bipyridyl complex (NN )Sc(2,2 -bipyridine) (Williams et al., 2010). 

Little work with scandium has been reported (401) and the actinide elements have been surprisingly neglected as far as bipyridyl and phenanthroline complexes are concerned (6< < ). 

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