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Nitrido-Ruthenium Cluster Complexes

We have already alluded to the diversity of oxidation states, the dominance of oxo chemistry and the cluster carbonyls. Brief mention should be made too of the tendency of osmium (shared also by ruthenium and, to some extent, rhodium and iridium) to form polymeric species, often with oxo, nitrido or carboxylato bridges. Although it does have some activity in homogeneous catalysis (e.g. of m-hydroxylation, hydroxyamination or animation of alkenes, see p. 558, and occasionally for isomerization or hydrogenation of alkenes, see p. 571), osmium complexes are perhaps too substitution-inert for homogeneous catalysis to become a major feature of the chemistry of the element. The spectroscopic properties of some of the substituted heterocyclic nitrogen-donor complexes may yet make osmium an important element for photodissociation energy research. [Pg.524]

Nitride, ruthenium cluster complex, 26 287 Nitrido, ruthenium clusters, 26 286 Nitrogen, iridium(III) complex, 26 119 Nitrosyls, molybdenum, 26 132 tungsten, 26 133... [Pg.362]


See other pages where Nitrido-Ruthenium Cluster Complexes is mentioned: [Pg.424]    [Pg.901]    [Pg.173]    [Pg.286]    [Pg.287]    [Pg.286]    [Pg.287]    [Pg.1025]   
See also in sourсe #XX -- [ Pg.8 , Pg.45 , Pg.64 , Pg.66 , Pg.70 , Pg.76 , Pg.78 , Pg.78 , Pg.80 ]

See also in sourсe #XX -- [ Pg.8 , Pg.45 , Pg.64 , Pg.66 , Pg.70 , Pg.76 , Pg.78 , Pg.78 , Pg.80 ]




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Cluster complexes

Nitrido

Nitrido Clusters

Nitrido complexe

Nitrido complexes

Nitrido ruthenium clusters

Ruthenium clusters

Ruthenium complex cluster

Ruthenium nitrido complexes

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