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Ruthenium-bipyridine complexes exchange reaction

Mechanism 2 requires deprotonation of a ligand, and dissociation of the hydrogen bound to the C(3) atom was suggested to be the slow step for the reaction of tris(2,2 -bipyridine)ruthenium(III) in base (12). This would require a mechanism for the 1,10-phenanthroline complexes different from that of the 2,2 -bipyridine complexes, but, from the data in Table II as illustrated in Figs. 3-5, this seems unlikely. The requirement of a different mechanism is based upon the significant differences in rates of D/H exchange as measured by 1H NMR for the tris(diimine)... [Pg.391]


See other pages where Ruthenium-bipyridine complexes exchange reaction is mentioned: [Pg.159]    [Pg.297]    [Pg.284]    [Pg.474]    [Pg.3751]    [Pg.52]    [Pg.128]    [Pg.24]    [Pg.207]   
See also in sourсe #XX -- [ Pg.118 ]




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Ruthenium complexes reactions

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