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Triggered molecular motions, rotaxanes

Figure 38 Molecular motions in copper(l)-complexed [2]-rotaxane (114) controlled by the redox state of the metal. In the Cu(I) state (114) the macrocycle is held at the phenanthroline site of the dumbbell. In the Cu(II) state (115) the macrocycle is held at the terpyridine site of the dumbbell. Therefore oxidation of Cu(I) to Cu(II) has triggered a translational motion of the complexed macrocycle along the dumbbell [29]. Figure 38 Molecular motions in copper(l)-complexed [2]-rotaxane (114) controlled by the redox state of the metal. In the Cu(I) state (114) the macrocycle is held at the phenanthroline site of the dumbbell. In the Cu(II) state (115) the macrocycle is held at the terpyridine site of the dumbbell. Therefore oxidation of Cu(I) to Cu(II) has triggered a translational motion of the complexed macrocycle along the dumbbell [29].
See other pages where Triggered molecular motions, rotaxanes is mentioned: [Pg.125]    [Pg.157]    [Pg.299]    [Pg.610]    [Pg.129]    [Pg.157]    [Pg.1787]    [Pg.1787]    [Pg.27]    [Pg.34]    [Pg.298]    [Pg.147]    [Pg.264]    [Pg.265]    [Pg.35]   
See also in sourсe #XX -- [ Pg.157 , Pg.158 , Pg.159 , Pg.160 , Pg.161 ]



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Molecular motion

Molecular rotaxanes

Rotaxans

Triggerable

Triggers

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