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Root-Mean-Square Radius

The procedure is obviously a very simple one, but suffers from the fact that the success rate diminishes very rapidly as the pore radius becomes smaller. The root-mean-square radius of gyration of... [Pg.170]

Figure 3. Partition coefficient of freely jointed chains between the bulk solution and a cylindrical pore. The chains have different numbers of mass-points (n) and different bond lengths, and are characterized by the root-mean-square radius of gyration measured in units of the pore radius. See text for details. Figure 3. Partition coefficient of freely jointed chains between the bulk solution and a cylindrical pore. The chains have different numbers of mass-points (n) and different bond lengths, and are characterized by the root-mean-square radius of gyration measured in units of the pore radius. See text for details.
For a statistical coil, the product of polymer intrinsic viscosity and molecular weight is directly proportional to the cube of the root-mean-square radius of gyration RG 77137... [Pg.335]

Figure 9 Scaling relationship between root-mean-square radius and molecular weight for polystyrene using GPC/MALLS. (From Wyatt, P. Hicks, D. L., Jackson, C., and Wyatt, G. K., Am. Lab., 20, 108,1988. With permission.)... Figure 9 Scaling relationship between root-mean-square radius and molecular weight for polystyrene using GPC/MALLS. (From Wyatt, P. Hicks, D. L., Jackson, C., and Wyatt, G. K., Am. Lab., 20, 108,1988. With permission.)...
Debye scattering deals with the situation wherein the relative size parameter is large. Since the root mean square radius of gyration of the particle, (s2)1/2, is a... [Pg.155]

An estimation of the local ligand concentration, [N]coii> could be achieved by assuming free movement of the ligands in the interior of a sphere with radius i, the root mean square radius of gyration of the polymer chain ... [Pg.16]

It is often convenient to express the growth law given by Eq. 15.39 in terms of a linear grain-size dimension. If f rms is the effective root-mean-square radius of the roughly equiaxed grains,... [Pg.378]

Fig.6 Temperature dependence of z-average root-mean square radius of gyration ((Pg>) and average hydrodynamic radius ( Rh)) of copolymers NIPAM-co-VP/60/5 and NIPAM-co-VP/30/5 in water, where the weight average molar masses are 2.9 x 106 and 4.2 x 106 g/mol, respectively [56]... Fig.6 Temperature dependence of z-average root-mean square radius of gyration ((Pg>) and average hydrodynamic radius ( Rh)) of copolymers NIPAM-co-VP/60/5 and NIPAM-co-VP/30/5 in water, where the weight average molar masses are 2.9 x 106 and 4.2 x 106 g/mol, respectively [56]...
Experimental Assessment, The most direct experimental assessment of the persistence length may be obtained from the root-mean-square radius of gyration measured by light scattering. The analytical expression for the unperturbed Rq of a. wormlike chain has been given by Benoit and Doty (5) ... [Pg.406]

Find the value of by iteration that satisfies equation 12, where x is given by equation 8. This value is Vgi, the root-mean-square radius at retention volume Vi. [Pg.127]

Figure 6. Log M versus local root-mean-square radius for a broad polystyrene standard (-----) and narrow polystyrene standards (m). Figure 6. Log M versus local root-mean-square radius for a broad polystyrene standard (-----) and narrow polystyrene standards (m).

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See also in sourсe #XX -- [ Pg.96 ]




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