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Ritter products, tertiary carbocations give

In the Ritter reaction a rather different kind of evidence for the cation is the fact that families of isomeric alcohols all give the same product. In all these cases, rearrangements of the first formed carbocation (Chapter 37) can easily account for the products. Another example in the decalin series is this Ritter reaction with KCN as the nitrile in acidic solution so that HCN is the reagent. The starting material is a spirocyclic tertiary alcohol but the product is a frans-decalin formed by... [Pg.1115]

See other pages where Ritter products, tertiary carbocations give is mentioned: [Pg.204]    [Pg.611]    [Pg.1244]    [Pg.971]    [Pg.382]   
See also in sourсe #XX -- [ Pg.204 ]



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