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Rhodium triethylphosphine

Figure 2.57 Interconversion between rhodium triethylphosphine complexes. Figure 2.57 Interconversion between rhodium triethylphosphine complexes.
Enantiomerically pure 2-alkylidenetetrahydrofurans were prepared by TiCl4 mediated reactions of 1,3-bis-silyl enol ethers with enantiomerically pure epichlorohydrin <06TA892>. Rhodium complexes as the one shown below reacted in solution in the presence of triethylphosphine to afford 2,2-disubstituted-5-methylenetetrahydrofurans in good yield <06JA9642>. [Pg.191]

B. Cetinkaya, M. F. Lappert, G. M. McLaughlin, and K. Turner, Chloromethylene-ammonium Chlorides. Electron-Rich Carbenoids as Precursors to Secondary Carbene Metal Complexes Crystal and Molecular Structure of Trichloro(dimethylamino-methylene)bis(triethylphosphine)rhodium(III), J. Chem. Soc., Dalton Tram. 1974, 1591-1599. [Pg.287]

O3C5H, Butanoic acid, 3-oxo-, methyl ester, rhodium complex, 27 292 03CIF3PtSC,3H3, Platinum(II), chlo-robis(triethylphosphine)(trifluoro-methanesulfonato)-, cis-, 26 126 O3CISWC3H, Tungsten, trichlorotrimeth-oxy-, 26 45... [Pg.405]

C20H3yClINPjPt, trans-Iodo(p-chloropheny1-methylisocyanide)bis(tri-ethylphosphine)platinum(II), 40B, 710 C20H37N20P2RhS2, Butanoylbis(triethylphosphine)(maleonitriledithio-lato)rhodium(III), 45B, 864... [Pg.396]

C2 4H6 2B2Fe02P4Pt2 f Di-(M hydroxy)-tetrakis(triethylphosphine)diplat-inum(II) tetrafluoroborate, 44B, 1065 C25H15N20PRhS2, Carbonyl(triphenylphosphine)(1-(ethylthio)maleonit-rile-2-thiolato)rhodium(I), 45B, 1348 C2 5H2 2AU2CI2P2 f (Bis(diphenylphosphino)methane)dichlorodigold, 43B, 1440... [Pg.628]

Bach and Cole-Hamilton (235) report that 1-hexene can be successfully hydroformylated in SCCO2 using triethylphosphine complexes of rhodium, and they point out that these catalysts would be significantly less expensive than the fluorinated analogues, such as those cited previously. For reaction conditions... [Pg.137]

See other pages where Rhodium triethylphosphine is mentioned: [Pg.220]    [Pg.132]    [Pg.679]    [Pg.220]    [Pg.132]    [Pg.679]    [Pg.193]    [Pg.173]    [Pg.186]    [Pg.76]    [Pg.217]    [Pg.375]    [Pg.420]    [Pg.14]    [Pg.255]    [Pg.98]    [Pg.391]    [Pg.420]    [Pg.448]    [Pg.117]    [Pg.408]    [Pg.644]    [Pg.176]    [Pg.274]   
See also in sourсe #XX -- [ Pg.132 ]



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Triethylphosphine

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