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Rhodium hydride, tetrakis oxidation

A similar selective oxidation can be carried out with tetrakis(triphenylphosphine)rhodium(I) hydride and an a, -unsaturated ketone as hydrogen acceptor, in this case the use of an optically active phosphine provided an enantioselective synthesis, although the levels of asymmetric induction were rather low (Scheme 10). ... [Pg.315]


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