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Rhodium complexes mixed oxidation state

The complexes of rhodium will primarily be considered in order of increasing oxidation state. However, complexes in which the oxidation state of the metal is uncertain (e.g. nitrosyls) or dinuclear complexes of mixed oxidation state will be dealt with last. [Pg.903]

MISCELLANEOUS RHODIUM COMPLEXES 48.10.1 Complexes of Mixed Oxidation State... [Pg.1065]

The synthetic strategy reported above (Eq. 6) has been previously employed for the preparation of mixed-valence RhlilRhl complexes containing the (/x-pz )(/x-Cl) moiety. Treatment of [(C5Me5)RhCl2(Hpz)] with [Rh(acac)(tfbb)J afforded 139, which was characterized by an X-ray crystal structure determination (79). This heterobridged complex contains two rhodium atoms in two different formal oxidation states (Rh111 and Rh1), with pseudooctahedral and square planar coordinations, respectively. [Pg.188]

See other pages where Rhodium complexes mixed oxidation state is mentioned: [Pg.422]    [Pg.104]    [Pg.216]    [Pg.790]    [Pg.229]    [Pg.74]    [Pg.115]    [Pg.134]    [Pg.219]    [Pg.200]    [Pg.94]   
See also in sourсe #XX -- [ Pg.1065 ]

See also in sourсe #XX -- [ Pg.4 , Pg.1065 ]



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