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Rhodium complexes carbon bonded adducts

Acetylenes with electronegative substituents reversibly combine with planar iridium(I) 93, 99) and rhodium(I) complexes (I) to form 1 1 adducts (XXII) (31). These are characterized by strong infrared absorption bands in the 1600-1800 cm region, apparently caused by a stretching mode of the coordinated acetylenic bond. The carbon-carbon bond order in these complexes may approach that of an olefin. In view of a recent... [Pg.65]


See other pages where Rhodium complexes carbon bonded adducts is mentioned: [Pg.128]    [Pg.48]    [Pg.34]    [Pg.106]    [Pg.77]    [Pg.581]    [Pg.66]    [Pg.51]    [Pg.428]    [Pg.1776]    [Pg.97]    [Pg.52]    [Pg.174]    [Pg.323]    [Pg.177]    [Pg.51]   
See also in sourсe #XX -- [ Pg.938 ]

See also in sourсe #XX -- [ Pg.4 , Pg.938 ]




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Carbon complex

Carbonate complexation

Carbonate) complexes

Complex adducts

Rhodium bonding

Rhodium carbon

Rhodium complexes bonding

Rhodium complexes carbon bonded

Rhodium complexes carbonates

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