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Rhenium di

It is in this oxidation state that the known chemistry of the two elements is most different. For rhenium di- and trinuclear cluster species predominate (Section 18-D-5), whereas for Tc there are only a few Tc and no Tc3+ complexes. Mononuclear Tc3+ species do occur. The only simple [MXJ3- complex known for either element is the [Tc(NCS)6]3 ion, but the mer-MCl3(PR3)3, MCl3py3, and [MX2(LL)2]+ complexes with X = halide, NCS , or MeS" and LL a diphosphine or diarsine are important.41 Some of these complexes can be reduced with retention of structure in the II and even I oxidation states.42... [Pg.993]

See other pages where Rhenium di is mentioned: [Pg.304]    [Pg.316]   
See also in sourсe #XX -- [ Pg.16 , Pg.27 ]

See also in sourсe #XX -- [ Pg.16 , Pg.27 ]

See also in sourсe #XX -- [ Pg.16 , Pg.27 ]



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Rhenium ] di-, with bonds

Rhenium ] di-, with quadruple bonds

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