Rhenium complexes azides

Rhenium nitrides have been reported for a wide range of Re-complexes including Rev, ReVI, and Revn. Azides, hydrazines, and NSC1 have all been utilized in the reaction wih Re111, ReIV, and ReVI1 to give the corresponding Rev nitrides (Eqs. (46-49) Scheme 6) [69-71]. 

---