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RhCl PMe

The analogous RhCl(PMe3)3 complexes react at RT with aliphatic and aromatic aldehydes in a reaction first order in aldehyde and Rh complex to give cis-hydridoacyl complexes , cis-HRh(CORXPMe3)3Cl. When pent-4-enol reacts with RhCl(PMe)3, the acylrhodium(lll) hydride can be isolated. However, it undergoes intramolecular cycliza-tion to cyclopentanone (half life, 1 h at 50°C) . [Pg.197]

See other pages where RhCl PMe is mentioned: [Pg.1029] [Pg.482] [Pg.483] [Pg.112]

See also in sourсe #XX -- [ Pg.2 , Pg.3 , Pg.166 ]

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RhCl