Rh complex catalyst

Carbon monoxide is compressed and sparged into the reactor riser. The reactor has no mechanical moving parts, and is free from leakage/ maintenance problems. The ACETICA Catalyst is an immobilized Rh-complex catalyst on solid support, which offers higher activity and operates under less water conditions in the system due to heterogeneous system, and therefore, the system has much less corrosivity. 

Tab. 4 The recycling efficiency of the 1-dodecene. PETPP (N = 18)/Rh complex catalyst hydroformylating...

In another report a semi-empirical rate equation has been proposed combining mechanisms of homogeneous and interfacial parameters for biphasic hydroformylation of 1-dodecene with water-soluble Rh-complex catalyst [36]. 

Tabata, M., T. Sone, and Y. Sadahiro. 1999. Precise synthesis of monosubstituted polyacetylenes using Rh complex catalysts. Control of solid structure and ir-conjugation length. Macro Chem Phys 200 265. 

Total surface areas (S) and average crystallite sizes (d) of the Rh complex catalysts ... 

Tabata, M. Sone, T. Mawatari, Y Yonemoto, D. Miyasaka, A. Fukushima, T. Sadahiro, Y. 3T-Conjugated columnar poly acetylenes prepared with Rh complex catalyst. Macromol. Symp. 2003, 192, 75-97. 

Tabata, M. Tanaka, Y Sadahiro, Y Sone, T. Yokota, K. Miura, 1. Pressure-induced cis to trans isomerization of aromatic polyacetylenes. 2. Poly((e-ethoxyphenyl)acetylene) stereoregularly polymerized using a Rh complex catalyst. Macromolecules 1997, 30, 5200-5204. 

Tabata, M. Takamura, H. Yokoto, K. Nozaki, Y. Hoshina, H. Minakawa, H. Kodaira, K. Pressure-induced cis to trans isomerization of poly(o-methoxyphenylacetylene) polymerized by Rh complex catalyst. A Raman, X-ray, and ESR study. Macromolecules 1994, 27, 6234—6236. 

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