Reversible addition-fragmentation transfer Single

Segmented terpolymers of poly(alkyl methacrylate)-g-poly(D-lactide)/poly(dimethylsiloxane) (PLA/PDMS) were prepared by combination of a grafting through technique (macromonomer method) and controlled/living radical polymerization such as atom transfer radical polymerization (ATRP) or reversible addition-fragmentation chain transfer polymerization. In a single-step approach, the low molecular weight methacrylate monomer (methyl methacrylate... [Pg.52]

Mballa Mballa MA, Ali SI, Heuts JPA, van Herk AM (2012) Control of the anisoUopic morphology of latex nanocomposites containing single montmorillonite clay particles prepared by conventional and reversible addition-fragmentation chain transfer based emulsion polymerization. Polym hit 61 861-865... [Pg.160]

The kinetic modeling of styrene controlled radical polymerization, initiated by 2,2 -asobis(isobutimitrile) and proceeding by a reversible ehain transfer meeha-nism was carried out and accompanied by addition-fragmentation in the presenee dibenzyltiitiocarbonate. An inverse problem of determination of the unknown temperature dependences of single elementary reaction rate eonstants of kinetic scheme was solved. The adequacy of the model was revealed by comparison of theoretical and experimental values of polystyrene molecular-mass properties. The influence of process controlling factors on polystyrene molecular-mass properties was studied using the model. [Pg.92]