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Retropinacoline rearrangement

The term "retropinacolinic rearrangement is commonly applied to such reactions, because the skeletal change formally reverses that occurring in the pinacol-pinacolone rearrange-... [Pg.137]

Wagner-Meerwein rearrangement of open-chain branched systems is occasionally termed the retropinacolin rearrangement. The classical example is the loss of water from 3,3-dimethyl-2-butanol, to give 2,3-dimethyl-2-butene ... [Pg.1085]

The reaction may be regarded as a vinylogous retropinacolin rearrangement that occurs by way of a mesomeric allyl cation. [Pg.1085]


See other pages where Retropinacoline rearrangement is mentioned: [Pg.381]    [Pg.384]    [Pg.1084]    [Pg.381]    [Pg.384]    [Pg.1084]   
See also in sourсe #XX -- [ Pg.226 ]




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Pinacolin and retropinacolin rearrangements

Retropinacolin rearrangement

Retropinacolin rearrangement

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