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Response Strategies for the Read-out of Information

Organometallic Components Ibr Organometallic Bioprobes Opening up the Advantages of IR-based Read-out Methods [Pg.220]

When several carbonyl ligands of the same type are present, vibrational coupling [23] will produce a more complicated IR spectrum in the 1900-2100 cm region. This is illustrated in Fig. 7.6. [Pg.223]

It can be seen from this discussion that the IR based read-out of information from organometallic bioprobes with carbonyl ligands by analysis of the vibrational band envelopes viewed through the window of the water background spectrum has a number of imusual features. The v(CO) signals are intense and narrow, can [Pg.225]

Now that the capabilities of the IR-read-out from LM(CO) responding groups have been introduced, more careful consideration can be made of the issues for bioprobe designs presented in Fig. 7.3. It has been established for some time [22, 38] that change in the solvation environment significantly influences the v(CO) signals (Fig. 7.7a). [Pg.226]


See other pages where Response Strategies for the Read-out of Information is mentioned: [Pg.217]    [Pg.217]   


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