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Resonance structures cations with positive charge adjacent

Allylic carbocations, like allylic radicals (Section 8.6), have a double bond next to the electron-deficient carbon. The allyl cation is the simplest allylic carbocation. Because the allyl cation has only one substituent on the carbon bearing the positive charge, it is a primary allylic carbocation. Allylic carbocations are considerably more stable than comparably substituted alkyl carbocations because delocalization is associated with the resonance interaction between the positively charged carbon and the adjacent tt bond. The allyl cation, for example, can be represented as a hybrid of two equivalent contributing structures. The result is that the positive charge appears only on carbons 1 and 3, as shown in the accompanying electrostatic potential map. [Pg.384]


See other pages where Resonance structures cations with positive charge adjacent is mentioned: [Pg.310]    [Pg.310]    [Pg.109]    [Pg.164]    [Pg.179]    [Pg.615]    [Pg.179]    [Pg.179]    [Pg.43]    [Pg.336]    [Pg.394]   


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Adjacency

Adjacency structure

Adjacent

Cation charges

Cation positions

Cationic structure

Cations with

Cations, charged

Charge resonance

Charge structural

Position, resonance

Positive charge

Positive charge structures)

Positively charged

Resonance structures

Structures cation

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