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Resonance, and Dienes

The overlap of p orbitals on three or more adjacent atoms allows electron density to delocalize, thus adding stability (16.1). [Pg.397]

An allyl carbocation (CH2=CHCH2 ) is more stable than a 1° carbocation because of p orbital overlap (16.2). [Pg.397]

In any system X=Y-Z , Z is sp hybridized to allow the lone pair to occupy a p orbital, making the system conjugated (16.5). [Pg.397]

Markovnikov s rule is followed. Addition of BT forms the more stable allylic carbocation. [Pg.398]

2-product is the kinetic product. When BT adds to the double bond, X adds to the end of the allylic carbocation to which it is closer (C2 not C4). The kinetic product is formed faster at low temperature. [Pg.398]

Radical Polymerization of CH2=CHZ 5 63 Chapter 16 Conjugation, Resonance, and Dienes... [Pg.1278]

See other pages where Resonance, and Dienes is mentioned: [Pg.570]    [Pg.572]    [Pg.574]    [Pg.576]    [Pg.578]    [Pg.580]    [Pg.582]    [Pg.584]    [Pg.586]    [Pg.588]    [Pg.590]    [Pg.592]    [Pg.594]    [Pg.596]    [Pg.598]    [Pg.598]    [Pg.600]    [Pg.602]    [Pg.604]    [Pg.1274]    [Pg.1276]    [Pg.1280]    [Pg.571]    [Pg.572]    [Pg.574]    [Pg.576]    [Pg.578]    [Pg.580]    [Pg.582]    [Pg.584]    [Pg.586]    [Pg.588]    [Pg.590]    [Pg.592]    [Pg.594]    [Pg.596]    [Pg.598]    [Pg.599]    [Pg.600]    [Pg.602]    [Pg.604]    [Pg.606]    [Pg.1276]    [Pg.1282]    [Pg.397]    [Pg.397]   


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