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Resolution Rhenium complexes

Rate-determining step, hydroformylation, 163 Reactivity, enantiomers, 286 Recognition, enantiomers, 278 Reduction and oxidation, 5 Reductive coupling, dissolving metal, 288 Reductive elimination, 5, 111 Resolution. See Kinetic resolution Rhenium-carbene complexes, 288 Rhodium-catalyzed hydrogenation, 17, 352 amino acid synthesis, 18, 352 BINAP, 20... [Pg.197]

Glaser oxidative coupling [Cu(OAc)2/py] of the rhenium ethynyls Re(C=CH)(NO)(PR3)Cp (R = Ph 248-250 tol, C6H4Bu -4251) affords the corresponding diyndiyls Re(NO)(PR3)Cp 2(p-C=CC=C) (96) as diaste-reotopic mixtures. Fractional crystallization leads to diastereotopic enrichment, or resolution for R = Ph, which permitted cystallographic assignment of the configuration. 13C-Labeled complexes were prepared and... [Pg.234]


See other pages where Resolution Rhenium complexes is mentioned: [Pg.239]    [Pg.170]    [Pg.333]    [Pg.296]    [Pg.29]    [Pg.387]    [Pg.387]    [Pg.396]    [Pg.609]   


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Resolution Rhenium

Rhenium complexes

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