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Relative Rates between Monohydroboration and Dihydroboration of Alkynes

Relative Rates between Monohydroboration and Dihydroboration of Alkynes [Pg.30]

The studies reveal that the ratio between (Eq. 4.9) and (Eq. 4.10) for terminal alkynes is relatively small, and this ratio for internal alkynes is much larger (Table 4.11) [2] and thus explains the much larger percentage of dihydroboration for terminal alkynes. In fact, the percentage of mono- and dihy- [Pg.30]




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Monohydroboration

Relative rates

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