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Relating to Reaction-Rate Theories

As a model of real behavior, the role of a theory is twofold (1) to account for observed phenomena in relatively simple terms (hindsight), and (2) to predict hitherto unobserved phenomena (foresight). [Pg.115]

What do we wish to account for and predict Consider the form of the rate law used for the model reaction A +. ..- products (from equations 3.1-8 and 4.1-3)  [Pg.115]

We wish to account for (i.e., interpret) the Arrhenius parameters A and EA, and the form of the concentration dependence as a product of the factors c (the order of reaction). We would also like to predict values of the various parameters, from as simple and general a basis as possible, without having to measure them for every case. The first of these two tasks is the easier one. The second is still not achieved despite more than a century of study of reaction kinetics the difficulty lies in quantum mechanical [Pg.115]

In many cases, reaction rates cannot be adequately represented by equation 6.1-1, but are more complex functions of temperature and composition. Theories of reaction kinetics should also explain the underlying basis for this phenomenon. [Pg.116]


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