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Rehm-Weller free energy relationship

Figure 14. Dependence of the Rehm-Weller free energy relationship on the intrinsic barrier AG. Key left, activation free energy change and right, transfer... Figure 14. Dependence of the Rehm-Weller free energy relationship on the intrinsic barrier AG. Key left, activation free energy change and right, transfer...
Determined by adaptation of the Rehm-Weller free energy relationship for photoinduced electron transfer. bRate constants for PhCH2SiMe3. The values in parentheses denote those for CH2=CHCH2SiMe3. Calculated using the free energy relationship for photoinduced electron transfer. [Pg.158]

The Rehm-Weller formulation of the free energy relationship in eq 17 can be rewritten as... [Pg.129]

Fig. 2. Plot of the fluorescence quenching rate constants k, vs the free energy changes AG for the electron transfer process (a) Marcus relationship, (b) Rehm-Weller relationship... Fig. 2. Plot of the fluorescence quenching rate constants k, vs the free energy changes AG for the electron transfer process (a) Marcus relationship, (b) Rehm-Weller relationship...
See other pages where Rehm-Weller free energy relationship is mentioned: [Pg.157]    [Pg.159]    [Pg.157]    [Pg.159]    [Pg.112]    [Pg.129]    [Pg.245]    [Pg.103]    [Pg.111]    [Pg.201]    [Pg.468]    [Pg.146]    [Pg.50]    [Pg.8]    [Pg.1513]    [Pg.162]   
See also in sourсe #XX -- [ Pg.134 , Pg.136 ]



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Energy relationships

Free energy relationships

Rehm-Weller relationship

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