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Reduction with Grignard reagents

The model is also meant to be applicable to reductions with Grignard reagents X = CH2 and M = halogenated Mg. [Pg.287]

Ethoxy-2-cyclohexenone is a useful intermediate in the synthesis of certain cyclohexenones. The reduction of 3-ethoxy-2-cyclohexenone with lithium aluminum hydride followed by hydrolysis and dehydration of the reduction product yields 2-cyclo-hexenone. Similarly, the reaction of 3-ethoxy-2-cyclohexenone with Grignard reagents followed by hydrolysis and dehydration of the addition product affords a variety of 3-substituted 2-cyclo-hexenones. ... [Pg.42]

Esters react with Grignard reagents to yield tertiary alcohols in which two of the substituents bonded to the hydroxyl-bearing carbon have come from the Grignard reagent, just as LiAlH4 reduction of an ester adds two hydrogens. [Pg.614]


See other pages where Reduction with Grignard reagents is mentioned: [Pg.36]    [Pg.69]    [Pg.23]    [Pg.36]    [Pg.69]    [Pg.23]    [Pg.537]    [Pg.84]    [Pg.71]    [Pg.562]    [Pg.563]    [Pg.583]    [Pg.609]    [Pg.636]    [Pg.638]    [Pg.676]    [Pg.722]    [Pg.732]    [Pg.733]    [Pg.750]    [Pg.808]    [Pg.825]    [Pg.831]    [Pg.834]    [Pg.838]    [Pg.838]    [Pg.901]    [Pg.903]    [Pg.905]    [Pg.260]    [Pg.96]    [Pg.1214]    [Pg.1216]   
See also in sourсe #XX -- [ Pg.603 ]

See also in sourсe #XX -- [ Pg.143 , Pg.173 ]




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Grignard reduction

Reduction reagents

With Grignard Reagents

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