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Non-innocent ligands redox

We finally point out that heteroleptic-dioxolene complexes with different redox non-innocent ligands can exhibit even further difficulty assignable redox changes.60... [Pg.353]

As briefly alluded to, there are different classes of redox-active ligands in addition to the above mentioned ones. For example, we have seen in Chapter 5, Section 8, that azo-groups (in particular, 2-(phenylazo)pyr-imidine) are able to undergo two separate one-electron reduction processes. Conjugated polynitriles (mnt, tcne, tcnq) also constitute an important class of redox-active molecules and the electrochemical behaviour of their metal complexes has been reviewed.107 The same holds as far as alkyldithiocarbamates (Rdtc) and their metal complexes are concerned,108 or nitrosyl complexes in their possible NO+[NO fNO redox sequence.109 Thus, we would like to conclude the present Chapter by discussing a few less known redox non-innocent ligands. [Pg.371]

Figure 1 Strategies of using redox non-innocent ligands in catalysis... Figure 1 Strategies of using redox non-innocent ligands in catalysis...
Strategy I. Redox non-innocent ligands used to modify the Lewis acid-base properties of the metal... [Pg.179]

Scheme 1 Ligand oxidation leading to increased Lewis acidity of the metal oxidation of hl by a Ir(lll) catalyst containing a redox non-innocent ligand... Scheme 1 Ligand oxidation leading to increased Lewis acidity of the metal oxidation of hl by a Ir(lll) catalyst containing a redox non-innocent ligand...
Figure 2 Redox non-innocent ligand supported Rh(l) catalysts employed in olefin hydrogenation... Figure 2 Redox non-innocent ligand supported Rh(l) catalysts employed in olefin hydrogenation...
Strategy II. Redox non-innocent ligands as electron reservoirs... [Pg.181]

Redox non-innocent ligands have also been employed in other kinds of processes. For example, a nickel-based system has been used in the purification of ethene gas streams [41]. The two forms (reduced and oxidized) of the dithiolene complex have different affinities for olefin, leading to separation of ethene from gas mixtures (Scheme 14). Intermediate 47 is obtained after electrochemical oxidation of the anionic nickel complex 46. The oxidized complex 47 reacts selectively with ethylene to form the adduct 48, thus the non-olefinic contamination of the multi-component stream... [Pg.192]

Scheme 14 Redox non-innocent ligands applied in ethene purification... Scheme 14 Redox non-innocent ligands applied in ethene purification...
Hindson K, de Bruin B (2012) Cooperative redox non-innocent ligands in directing organometallic reactivity (Eur. J. Inorg. Chem. 3/2012). Eur J Inorg Chem 2012 340-342... [Pg.223]

Lyaskovskyy, V. de Bruin, B. Redox non-innocent ligands Versatile new tools to control catalytic reactions. ACS Cat. 2012,2,270-279. [Pg.123]

See other pages where Non-innocent ligands redox is mentioned: [Pg.325]    [Pg.382]    [Pg.12]    [Pg.12]    [Pg.176]    [Pg.176]    [Pg.177]    [Pg.177]    [Pg.179]    [Pg.179]    [Pg.181]    [Pg.181]    [Pg.183]    [Pg.185]    [Pg.187]    [Pg.188]    [Pg.189]    [Pg.191]    [Pg.193]    [Pg.195]    [Pg.195]    [Pg.197]    [Pg.199]    [Pg.201]    [Pg.201]    [Pg.203]    [Pg.467]    [Pg.44]    [Pg.674]    [Pg.362]   
See also in sourсe #XX -- [ Pg.325 ]

See also in sourсe #XX -- [ Pg.12 ]

See also in sourсe #XX -- [ Pg.433 , Pg.467 ]

See also in sourсe #XX -- [ Pg.45 ]



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Cooperative and redox non-innocent ligands

Innocent ligand

Innocents

Ligands innocent ligand

NON ligands

Redox Non-innocent Ligands Reactivity and Catalysis

Redox ligand

Strategy II. Redox non-innocent ligands as electron reservoirs

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