Redox active molecular orbital RAMO

Fig. 30.2 Schematic pictures of the Ou and ti redox active molecular orbitals (RAMOs) (a) and the o and states (b)...

Fig. 30.4 o and redox active molecular orbitals (RAMOs) of the 1V54B and 1V540 models of the Cua site in the gas phase. AU isovalue surfaces are set at 0.03 (e/A ). Molecular structures are shown in thin lines... 

Valence PES data for [FeCy have been used to probe the MO structure of the ferrous site (Figure 9). The general shape of the photoelectron spectrum is quite similar to that for the ferric species except for a new peak on the low binding-energy side (labeled redox-active molecular orbital (RAMO)). That peak corresponds with the extra electron in the ferrous species, the lone electron in the 3 manifold. Although the overall shapes of the spectra are similar, the variable photon energy behavior is quite different in the ferrous relative to the ferric site. In the ferrous... 

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