Rearrangement of hydroperoxides

Rearrangement of Hydroperoxides C-Alkyl- O-hydroxy-elimin ation... [Pg.1418]

Drivers for Performing Rearrangements of Hydroperoxides in Micro Reactors... [Pg.538]

Beneficial Micro Reactor Properties for Rearrangement of Hydroperoxides... [Pg.539]

Rearrangements of Hydroperoxides Investigated in Micro Reactors Organic synthesis 82 [OS 82] Rearrangement of cumene hydroperoxide... [Pg.539]

The rearrangements of hydroperoxides are acid-catalyzed and are analogous to carbocation rearrangements except that positive oxygen (with only six valence electrons) instead of positive carbon is involved in the intermediate... [Pg.722]

Anderson GH, Smith J. Acid-catalyzed rearrangement of hydroperoxides. II. Phenylcycloalkyl hydroperoxides. Can J Chem 1968 46 1561-1570. [Pg.231]

Rearrangement of hydroperoxides. Migration to electron-deficient oxygen... [Pg.893]

C R I E G E E Rearrangement Rearrangement of hydroperoxides to ester ketals or 1,3-diols. [Pg.77]

The current explanation of the rearrangement of hydroperoxides with double-bond stereomutation is set out in Scheme 10.7. For example, allylic radical lA gives rise to two peroxy radicals 2A and 2B. Of these 2A is the precursor of the 9-hydroperoxide. If, however, bond rotation occurs followed by regeneration of the allyl radical 2C this, via the 13-peroxy radical, can furnish either the 13-hydro-peroxide or a cyclic peroxide. [Pg.455]

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