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Rearrangement to nitriles

Isocyanides, when heated in the gas phase or in nonpolar solvents, undergo a 1,2-intramolecular rearrangement to nitriles RNC — RCN. In polar solvents the mechanism is different. [Pg.1421]

Terminal vinyl azides give, upon decomposition, vinylnitrenes which can stabilize by rearrangement to nitriles. The pyrolysis of jS-styryl azide (73) afforded in this manner phenylacetonitrile (74) (74%) Nitriles were also obtained from a-azidoketenes (75) gene-... [Pg.348]

See also in sourсe #XX -- [ Pg.280 ]



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Nitriles rearrangement

To nitrile

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