Rearrangement stannane-mediated

There are numerous reports of stannane-mediated free-radical chemistry that does not fit neatly into the categories discussed above738-801. Some of these publications describe unusual outcomes and chemistry that is specific to a small subset of substrates, while others report radical rearrangements and fragmentations that take place after the initial, tin-mediated, radical-forming event. We have chosen a small set of examples that illustrate these concepts. 

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