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Rearrangement spin-equilibrated

As discussed above, the original impetus for our TRIR investigation of diazoester 6 was to monitor directly the kinetics of rearrangement to ketene 8. Specifically, we were interested in determining the portion of ketene 8 produced directly from the singlet excited state of 6 and that formed from spin-equilibrated carbene 7 (Scheme 2.8). Because the lifetime of 6 is likely much less than 1 ns and cer-... [Pg.64]

See other pages where Rearrangement spin-equilibrated is mentioned: [Pg.288]    [Pg.91]    [Pg.229]    [Pg.820]    [Pg.230]    [Pg.820]    [Pg.193]    [Pg.179]    [Pg.272]    [Pg.91]    [Pg.272]    [Pg.357]    [Pg.287]    [Pg.213]   
See also in sourсe #XX -- [ Pg.97 , Pg.223 ]



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