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Rearrangement of a-Thio Substituted Allylic Esters

General Procedure. 2-tert-Butylthio-3-Vinylnonanoic Acid (201) [Pg.288]

In connection with a synthesis directed towards the lanostane skeleton 204, Watt et al. used the Ireland-Claisen rearrangement of 202 as key step to introduce the quaternary center in 203 stereoselectively [118]. The diastereoselectivity of the [Pg.288]

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7-substituted 4-thio

A -Allylations

A rearrangements

A-allylation

Allyl esters rearrangements

Allyl rearrangement

Allylation esters

Allylic esters rearrangements

Allylic rearrangement

Allylic substitution

Ester rearrangements

Esters a-substitution

Esters allyl

Esters allylic

Of allyl ester

Substitution esters

Substitution rearrangement

Substitutive rearrangement

Thio esters

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