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Reactivity of hydroxyl groups

Stacey, M. See also, Overend, W. G. Sugihara, James M., Relative Reactivities of Hydroxyl Groups of Carbohydrates, VIII, 1-44... [Pg.459]

That steric factors alone cannot account for the reactivity of hydroxyl groups was indicated by the unimolar p-toluenesulfonylation of l,4 3,6-dianhydro-D-glucitol.23 The major product, the 5-p-toluenesulfonate (45%), is derived by reaction at the sterically hindered endo-hydroxyl group, and the exo-2-p-toluenesulfonate was isolated in only 12% yield. Although the more reactive HO-5 (es-... [Pg.14]


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See also in sourсe #XX -- [ Pg.497 ]




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