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Reactivity and Modifications

Moreover, the stability of the QM pincer complexes allows selective modifications of both the metal center and the carbonyl part of the quinone methide moiety, still with [Pg.70]

An additional notable mode of the reactivity of these quinone methide complexes is formation of metal stabilized p- and o-xylylenes.10 [Pg.72]

A similar approach to the one described above was utilized for the formation of quinone methide derivatives of osmium.14 Reaction of OsCl2(PPh3)3 with a phenolic diphosphine ligand in the presence of Et3N resulted in phosphine exchange followed by C—H activation and deprotonation by the base to form the two isomeric QM [Pg.72]


See other pages where Reactivity and Modifications is mentioned: [Pg.70]    [Pg.249]    [Pg.1018]    [Pg.211]   


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Reactivity and Chemical Modification of Polymers

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