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REACTIONS WITH ELECTROPHILIC OXYGEN AND SULPHUR

Following the procedure previously described and briefly reported in the method section, we found (at PWP level) that the Fukui index associated with orbital lone pair of oxygen in sulfine, has the value of 0.04 eV, while those associated with carbon and sulphur, are 0.19 and 0.21 eV, respectively. Speaking in terms of hard-soft theory of Pearson, we can indicate the orbital with the lowest Fukui index as the most reactive in the electrophilic reaction with H" ". [Pg.104]

See other pages where REACTIONS WITH ELECTROPHILIC OXYGEN AND SULPHUR is mentioned: [Pg.54]    [Pg.55]    [Pg.57]    [Pg.59]    [Pg.61]    [Pg.63]    [Pg.65]    [Pg.67]    [Pg.69]    [Pg.71]    [Pg.73]    [Pg.75]    [Pg.77]    [Pg.79]    [Pg.81]    [Pg.274]    [Pg.383]    [Pg.54]    [Pg.55]    [Pg.57]    [Pg.59]    [Pg.61]    [Pg.63]    [Pg.65]    [Pg.67]    [Pg.69]    [Pg.71]    [Pg.73]    [Pg.75]    [Pg.77]    [Pg.79]    [Pg.81]    [Pg.274]    [Pg.383]    [Pg.217]    [Pg.254]    [Pg.254]    [Pg.109]    [Pg.374]    [Pg.106]    [Pg.225]    [Pg.87]    [Pg.313]    [Pg.519]   


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Electrophilicity, and

Oxygen and sulphur

Oxygen sulphur

Reaction with oxygen

Reactions with electrophiles

Reactions with electrophilic oxygen

Reactions with electrophilic sulphur

Sulphur electrophiles

Sulphur reactions

With Electrophiles

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