Reactions of Si-Fluorinated 1,3,5-Trisilacyclohexanes

Si-fluorinated derivatives of 1,3,5-trisilacyclohexane behave in a totally similar fashion [124]. The presence of a CCI2 group causes reaction according to 

Reaction of 3 mole equivalents of MeMgCl with 302 produces 3, which in turn reacts with LiAlH yielding 304. 

Si-fluorinated 1,3,5-trisilacyclohexanes containing two CCI2 groups will undergo Si-methylation  

MeoSi SiMeo 1 Cl-C-5— C- l P2 MeMgCl C MeoSi SiMeo X Cl SiMe3 MeoSi SiMeo X SiMe3 

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