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Reaction classification radical oxidative additions

The mechanisms of the usual organic reactions are now clearly established, and the reactions are classified as ionic, radical, and molecular. More detailed classifications have also been made. The mechanisms of many reactions involving non-transition metal compounds are clear enough for example, in the Grig-nard or Reformatsky reaction, the first step is the irreversible oxidative addition of alkyl halides to form Mg-carbon or Zn-carbon bonds, in which the carbon is considered to be a nucleophilic center or carbanion which reacts with various electrophiles. [Pg.42]

In addition to the classification of inhibitors according to their mechanisms of the action on oxidation, they can be classified into consumable and long-lived inhibitors. A consumable inhibitor is irreversibly consumed in its reactions with free radicals (R or RCV) or hydroperoxide. The stoichiometric coefficient of inhibition of such inhibitors is typically equal to one or two per inhibitory functional group. However, in some systems (for example RH 02 InH), an inhibitor can act cyclically so that, getting repeatedly regenerated, the... [Pg.490]


See other pages where Reaction classification radical oxidative additions is mentioned: [Pg.8]    [Pg.724]    [Pg.67]    [Pg.133]    [Pg.2]    [Pg.8]   
See also in sourсe #XX -- [ Pg.101 ]




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Addition-oxidation reactions

Additives classification

Oxidation oxidative addition reaction

Oxidation radical

Oxidation radical addition reactions

Oxidative addition reactions

Oxidative radical reaction

Oxide Radicals

Oxides classification

Radical reaction addition

Radical reactions oxidation

Reaction classification

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