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Enols racemization via

In aqueous buffers GDH exhibits only low enantioselectivity, e.g. for the kinetic resolution of l-phenyl-l,2-ethanediol (which is most probably due to spontaneous racemization via enolization)[74] furthermore, it suffers from pronounced product inhibition, accounting for low yields. Both problems (product inhibition and... [Pg.1122]

With respect to chiral stability amino acids are fairly insensitive to acids and bases. Racemization via enolization of carboxylic acids in acidic solutions involves protonation of the carbonyl oxygen... [Pg.115]


See also in sourсe #XX -- [ Pg.768 ]

See also in sourсe #XX -- [ Pg.768 ]

See also in sourсe #XX -- [ Pg.768 ]

See also in sourсe #XX -- [ Pg.714 ]

See also in sourсe #XX -- [ Pg.906 ]




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Enols racemization

Racemization via enolization

Racemization via enolization

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