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Quinoxaline 3- cyano-, preparation

Cyano derivatives of (18) are prepared by reaction of o-phenylenediamine with o-CcH4(CO)2N(CH2) COC(CN)=NC6H4NMe2-p. Hydrolysis of the latter compounds give intennediates of the type o-C H4(CO)2N(CH2) COCOCN which on condensation with o-phenylenediamine yield 3-phthalimidoalkylquinoxalin-2-ones. 6,7-Disubstituted quinoxalines have been prepared from 2,4-diazido-1,5-dinitrobenzene (19), which on pyrolysis is converted into 2-azido-... [Pg.111]

Taylor EC, Maiyanoff CA, Skotnicki JS (1980) Heterocychzation with cyano and sulfonyl epoxides. Preparation of quinoxalines and tetrahydroquinoxahnes. J Org Chem 45(12) 2512-2515. doi 10.1021/jo01300a053... [Pg.129]


See other pages where Quinoxaline 3- cyano-, preparation is mentioned: [Pg.130]    [Pg.135]    [Pg.200]    [Pg.83]    [Pg.114]    [Pg.2335]   
See also in sourсe #XX -- [ Pg.208 ]

See also in sourсe #XX -- [ Pg.208 ]

See also in sourсe #XX -- [ Pg.208 ]




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Quinoxalines, preparation

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