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Pyrazine-bridged complexes

The pyrazine-bridged complex [OsRu(pyz)bipy4Cl2]2+ has been reported and its electronic spectrum and cyclic voltammetry have been measured two one-electron oxidations are observed.112 In recent work the X-ray crystal structure of [0s2(pyz)(NH3)1(l]Cl6-2H20 has been determined the Os —N (pyrazine) distance is 2.101(7) A.I14b... [Pg.537]

The triflato complex [0s(NH3)5(0S02CF3)], made from [Os(NH3)s(N2)fand triflic acid with bromine, is a very useful precursor for the preparation of mononuclear [Os(NH3)5L]" species (L = pyridine, pyrazine, pyrimidine, etc., see p. 534) and for binuclear pyrazine-bridged complexes (p. 526). For ran5-[0s02(NH3)4], see p. 582. [Pg.529]

See other pages where Pyrazine-bridged complexes is mentioned: [Pg.172]    [Pg.124]    [Pg.224]    [Pg.320]    [Pg.529]    [Pg.536]    [Pg.1192]    [Pg.3348]    [Pg.313]    [Pg.1191]    [Pg.3347]    [Pg.320]    [Pg.536]    [Pg.3774]    [Pg.3983]    [Pg.3990]    [Pg.658]    [Pg.707]    [Pg.710]    [Pg.711]    [Pg.712]    [Pg.715]    [Pg.721]    [Pg.308]    [Pg.11]   
See also in sourсe #XX -- [ Pg.783 , Pg.896 ]

See also in sourсe #XX -- [ Pg.821 , Pg.992 ]



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