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Purely attractive or repulsive chains existence of continuous models

1 Purely attractive or repulsive chains existence of continuous models [Pg.651]

It would be very difficult to analyse the interaction between polymer and solvent in detail, at a given temperature. Actually, this would also be useless, if we want only to predict the properties of solutions of long polymers. In fact, the [Pg.651]

The arrows show the limits of the 0 domain (tricritical domain). [Pg.652]

Let us examine which model can be chosen to represent a chain the links of which are partially attractive. First, let us consider chains with N links (N 1) on a d-dimensional square lattice, starting from an origin O. We assume that the weight associated with such a chain is [Pg.652]

JV g 1 has a Kuhnian behaviour (chains in good solvent). What happens if u 0  [Pg.653]




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Chain repulsion

Continuous model

Purely attractive model

Repulsive model

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